First right click on desktop shortcut or on any start
menu program and choose Properties from the menu.
Here under the
shortcut tab, click in Shortcut key box.
Now press any key
on your keyboard that you want to use as combination with
CTRL+ALT. For example, if you want to create
keyboard shortcut to open MSN Messenger, simply press 9, your keyboard
shortcut for MSN Messenger will be CTRL+ALT+9.
Now
press OK and test your shortcut key.